Personally i think most of them are a con, Proboost works in cars running on throttle bodies, but i wonder about others. High octane fuel is fine if the car is designed to run on High octane fuel, as many are, Scoobies, evos, etc etc, but for a car with a normal 93/95 RON setup (or plug if its a vauxhall), then your wasting your money on onctane boosters.
If you were to have your car chipped then indeed runing high octane fuel would see better fule economy and icreased performance, as from factory cars are designed to run on dirty fuel to accomodate for poor fuel cleanliness (which is comon in some foreig countries). However here, we have clean fuel, and chipping a car sets the car up to run on clean fuel only, hence the better economy.