the best sound you can get from your car without spending thousands, and having to learn a whole load of shit to get the right set up is a simple install
which means a set of comps, mids and tweeters and a sub, and a amp of course
in both my almera and runabout I run the system like this, in both you can hear the music in the back, although the sub or subs tend to be very over powering
the only way around this if your that intent on supplying your rear passengers with a better sound is by installing rear speakers, but by doing this you will mess up your sound stage, and you end up hearing the rears slightly after the fronts because of the distance between your ears and the speakers
when you start putting a centre speaker in, or running 3 way comps things just get even more complicated with getting the sound right
one of the lads who I competed with won his league every year for about 5 years running a set of 2 way comps, all different systems but same basic idea, he then went and ran a set of 3 ways active, and his sound scores went drastically down, he just couldnt get it right, and this is with the other lads on the team helping out too(all league winners in their own league), and between their knowledge couldnt help either
he went back to the 2 way comps and won the euro championship league
the best solution for you would be to install some rear speakers in the oem placements and run them off the headunit, and use the fader on the headunit to fade them out when theres no one in the back, and fade them in when people are in the back
but by using the fader on the headunit this can also mess up the sound a bit, and if your pre-outs thats running the subs are rear pre-outs you cant fade the rear speakers out without fading the sub out too, so another solution would be to physically disconnect the speakers when theres no one in the back
when i used to have a screen in the rear I installed 6x9's and ran them off an amp, I used a switch on the tailgate to operate the remote wire on the amp that powered the 6x9's so when the boot was open the 6x9's would work and I would have a good and loud sound coming out of the car so people could hear whatever dvd I had on, you could do a similar idea to this and just have the switch in the front of your car