Thank you nugget, its been a long road but it has paid off.
Still have slight overheating issues, originally i blanked off the heater matrix pipes but turns out this caused it to overheat whilst motorway driving. Last night i added in a pipe and removed the thermostat and Re-filled the coolant which showed much improvement but after a few hours and then driving around town the temperature started to go high and was temperamental!
Back up today to hopefully get any last air from inside and hope thats the issue, otherwise ill need to start looking at any blockages/water pump and headgasket. Im suggesting headgasket purely because on the MOT retest at the fast idle test the temperature went up pretty fast and reached the red, on the first MOT i wasnt there to see and it wasnt long after driving away i started to have the problems...